张 文 雄 博士,教授,博士生导师 研究方向:配位化学、稀土金属有机化学和元素有机化学 办公室:化学楼A630 办公室电话:010-6275-8294 电子信箱:wx_zhang@pku.edu.cn 教育和工作经历: 2021.01-至今 PI,伟德国际1946官网化学学院无机所工作,博雅特聘教授 2018.01-2020.12,伟德国际1946官网化学学院有机所工作,博雅特聘教授 2016.08-2017.12,伟德国际1946官网化学学院有机所工作,教授 2009.10-2009.12,日本理化学研究所客座研究员 2007.10-2016.07,伟德国际1946官网化学学院有机所工作,副教授 2004.11-2007.09,日本理化学研究所博士后 2004.01-2004.03,日本北海道大学JST研究员 2002.10-2004.10,伟德国际1946官网化学学院博士后 1999.09-2002.09,南开大学化学学院,理学博士 1996.09-1999.06,广西师范大学化学与药学学院,理学硕士 1992.09-1996.07,湖南师范大学化学化工学院,化学教育学士 部分荣誉及奖励: 2019年获宝钢优秀教师奖 2019年获伟德国际1946官网优秀博士学位论文指导教师 2017年获国家杰出青年科学基金 2016年获杨芙清王阳元院士优秀教学科研奖 2015年获Thieme Chemistry Journals Award 部分社会服务与学术兼职: 2023- Organometallics, Member of Editorial Advisory Board 2019- Green Synthesis & Catalysis (Elsevier B. V.)副主编 2019- Chinese Chemical Letters (CCL) 编委 2019- Chemical Research in Chinese Universities青年编委 2018- Chinese Journal of Organic Chemistry编委 2017- Chinese Journal of Chemistry 青年编委 2023- 中国化学会磷化学专业委员会副主任委员 2023- 中国化学会第三十一届理事会有机化学学科委员会委员 2020- 中国化学会高级会员 2020- 中国稀土学会稀土分子材料与超分子器件专业委员会委员 2019- 北京化学会第十八届理事会理事 2018- 衡阳师范学院客座教授 2017- 湖北大学有机功能分子合成与应用教育部重点实验室学术委员会委员 2017- 广西师范大学客座教授 2016- 中国晶体学会第一届监事会监事
代表性论文:
(*: Corresponding author, #: Authors contributed equally)
1. Yu Zheng#, Chang-Su Cao#, Wangyang Ma#, Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi, 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins,
J. Am. Chem. Soc. 2020, 142, 10705-10714.
2. Yang Wang*, Wen-Xiong Zhang*, and Zhenfeng Xi, Carbodiimide-Based Synthesis of N-Heterocycles: Moving from Two Classical Reactive Sites to Chemical Bond Breaking/Forming Reaction,
Chem. Soc. Rev. 2020, 49, 5810-5849.
3. Nan Li#, Botao Wu#, Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*, Trishomoaromatic (B3N3Ph6) Dianion: Characterization and Two-Electron Reduction,
Angew. Chem. Int. Ed. 2020, 59, 8868-8872.
4. Ze-Jie Lv, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang*, and Zhenfeng Xi, Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity,
J. Am. Chem. Soc. 2019, 141, 20547-20555.
5. Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation,
J. Am. Chem. Soc. 2019, 141, 8773-8777.
6. Shanshan Du#, Jimin Yang#, Jingyuan Hu, Zhengqi Chai, Gen Luo, Yi Luo, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P−C Bonds,
J. Am. Chem. Soc. 2019, 141, 6843-6847.
7. Jianhao Yin#, Jiapeng Li#, Gao-Xiang Wang#, Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi*, Dinitrogen Functionalization Affording Chromium Hydrazido Complex,
J. Am. Chem. Soc. 2019, 141, 4241-4247.
8. Shanshan Du, Jianhao Yin, Yue Chi, Ling Xu, and Wen-Xiong Zhang*, Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P3 Complexes,
Angew. Chem. Int. Ed. 2017, 56, 15886-15890.
9. Baosheng Wei, Liang Liu, Wen-Xiong Zhang*, and Zhenfeng Xi, Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca4[O] Inverse Crown Ether Complex,
Angew. Chem. Int. Ed. 2017, 56, 9188-9192.
10. Liang Liu, Miaomiao Zhu, Hai-Tao Yu, Wen-Xiong Zhang*, and Zhenfeng Xi*, Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation,
J. Am. Chem. Soc. 2017, 139, 13688-13691.
11. Yongliang Zhang, Junnian Wei, Yue Chi, Xuan Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Spiro Metalla-aromatics of Pd, Pt, Rh: Synthesis and Characterization,
J. Am. Chem. Soc. 2017, 139, 5039-5042.
12. Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes,
Chem. Sci. 2017, 8, 6852-6856.
13. Wangyang Ma#, Chao Yu#, Tianyang Chen#, Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Metallacyclopentadienes: Synthesis, Structure and Reactivity,
Chem. Soc. Rev. 2017, 46, 1160-1192.
14. Liang Liu, Junnian Wei, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts,
Angew. Chem. Int. Ed. 2016, 55, 14762-14765.
15. Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Synthesis of Phospholyl Lithium from White Phosphorus,
Angew. Chem. Int. Ed. 2016, 55, 9187-9190.
16. Kunbing Ouyang, Wei Hao, Wen-Xiong Zhang*, and Zhenfeng Xi, Transition-Metal-Catalyzed Cleavage of C–N Single Bonds,
Chem. Rev. 2015, 115, 12045-12090.
17. Yang Wang, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp3)–H bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides,
J. Am. Chem. Soc. 2012, 134, 2926-2929.
18. Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi*, Zirconocene and Si-Tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis,
Acc. Chem. Res. 2011, 44, 541-551.
19. Yang Wang, Wen-Xiong Zhang*, Zitao Wang, and Zhenfeng Xi*, Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and their Selenium and Tellurium Derivatives by Convergent Tandem Annulation,
Angew. Chem. Int. Ed. 2011, 50, 8122-8126.
20. Zitao Wang, Yang Wang, Wen-Xiong Zhang*, Zhaomin Hou, and Zhenfeng Xi*, Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur, and Carbodiimides,
J. Am. Chem. Soc. 2009, 131, 15108-15109.