王哲明 教授

无机化学，功能配位化学，晶体工程

电话：010-62755926
传真：010-62751708
电子信箱：zmw@pku.edu.cn

王哲明，男，教授，1962年11月生，出生地：福建省龙岩市

学习经历

1979-1983年，伟德国际1946官网理学学士（放射化学）
1985-1989年，福州大学理学硕士（物理化学）
1993-1996年，伟德国际1946官网理学博士（物理化学）

工作经历

1983-1985年，化工部青岛劳动保护研究所，助理工程师
1889-1993年，福州大学化学系，讲师
1996-至今，伟德国际1946官网，博士生导师（2005年），教授（2006年）
2002-2003年，日本冈崎国立共同研究机构，分子科学研究所，日本文部省COE访问副教授

主讲课程：

高等无机化学（研究生），X-射线晶体学和单晶结构分析（研究生），中级无机化学实验（化学专业本科生），结构与物性（物理专业本科生）

目前主要研究领域和兴趣：

1. 分子间相互作用和超分子组装；超分子聚集体的形和拓扑
2. 磁性、电性功能材料，多孔磁性材料，晶体工程等

近年来在具有新颖拓扑特性的配位聚合物及其磁性，多卤素与生物氮碱组装的纳米结构，多核稀土配合物，新的分子间相互作用类型，多功能分子磁性材料等方面的研究中得到了一系列的成果，有关工作发表在Adv. Funct. Mater., Chem. Asian J., Chem. Mater., Adv. Mater., Inorg. Chem., Angew. Chem. Int. Ed., New J. Chem., J. Am. Chem. Soc., Dalton Trans., CrystEngComm, ChemCommun.等期刊上。

研究工作得到国家科技部国家重点基础研究发展规划项目（G1998061310，2006CB601102）、国家自然科学基金委青年基金（29701001），国家自然科学基金委面上项目（90201014，20571005）、创新群体项目（20221101）和重大项目（20490210）等基金资助。

自1986年起以单晶X-射线衍射作为主要研究手段从事科学研究工作。研究领域涉及固体化学，功能配位化学，材料化学，超分子化学，晶体工程和蛋白质晶体学。与合作者发表研究论文百余篇。

近年来发表论文：

2008

1. Liu T, Zhang YJ, Wang ZM*, Gao S*, “A 64-nuclear cubic cage incorporating propeller-like Fe^III₈ apices and HCOO^- edges”, J. Am. Chem. Soc. 2008, 130, 10500-10501.
2. Yao JY, Xiao Z, Gan LB*, Yang DZ, Wang ZM*, “Towards the Rational Synthesis of Norfullerenes. Controlled Deletion of One Carbon Atom from C₆₀ and Preparation of 2,5,9-Trioxo-1-nor(C₆₀-I_h)[5,6]fullerene C₅₉(O)₃ Derivatives”, Org. Lett. 2008, 10, 2003-2006.
3. Yang XB, Gan LB*, Wang ZM*, “Controlled regio- and chemoselective addition of isothiocyanate to the dione moiety of a cage-opened fullerene-mixed peroxide derivative”, Chem. Commun. 2008, 1980-1982.
4. Liu T, Yang YF, Wang ZM*, Gao S*, “Two diammonium copper azides with similar layerlike magnetic substructures made of chains of serially connected Cu₆ rings show cation-modulated magnetism”, Chem. Asian J. 2008, 3, 950-957.
5. Wang XY, Wang ZM, Gao S*, “Detailed magnetic studies on Co(N^-₃)₂(4-acetylpyridine)₂: a weak-ferromagnet with a very big canting angle”, Inorg. Chem. 2008, 47, 5720-5726.
6. Liu T, Wang BW, Chen YH, Wang ZM*, Gao S*, “Syntheses, structures and magnetic properties of two mixed-valent disc-like hepta-nuclear compounds of [(Fe^IIFe₆^III)(tea)₆](ClO₄)₂ and [(Mn^II₃Mn^III₄)(nmdea)₆(N₃)₆]·CH₃OH (tea = N(CH₂CH₂O)₃^3-, nmdea = CH₃N(CH₂CH₂O)₂^2-)”, Zeit. Anorg. Allge. Chem. 2008, 634, 778-783.
7. Wang XY, Wang ZM, Gao S*, “Constructing magnetic molecular solids by employing three-atom ligands as bridges”, Chem. Commun. 2008, 281-294.

2007

1. Wang ZM*, Zhang XY, Batten SR*, Kurmoo M*, Song Gao*, “[CH₃NH₂(CH₂)₂NH₂CH₃][M₂(HCOO)₆] (M=Mn^II and Co^II): Weak ferromagnetic metal formate frameworks of unique binodal 6-connected (4¹²·6³)(4⁹·6⁶) topology, templated by a diammonium cation”, Inorg. Chem. 2007, 46, 8439-8441.
2. Xu HB, Wang BW, Pan F, Wang ZM, Gao S*,, “Stringing oxo-centered trinuclear [Mn^III₃O] units into single-chain magnets with formate or azide linkers”, Angew. Chem. Int. Ed. 2007, 46, 7388-7392.
3. Xiao Z, Yao JY, Yang DZ, Wang FD, Huang SH, Gan LB,* Jia ZS, Jiang ZP, Yang XB, Zheng B, Yuan G, Zhang SW, Wang ZM*, “Synthesis of [59]Fullerenones through Peroxide-Mediated Stepwise Cleavage of Fullerene Skeleton Bonds and X-ray Structures of Their Water-Encapsulated Open-Cage Complexes”, J. Am. Chem. Soc. 2007, 129, 16149-16162.
4. Pan F, Wang ZM, Gao S*, “Magneto-Structural Correlation in a Series of Bimetallic Alternating Chain Complexes of [Cr^IIIL(CN)₄]_n[Mn^III(salpn)]_n·nSolvents (L = 2,2’-bipy or 9,10-phen, salpn = Substituted Salicyldehyde, Solvents = Water and Methanol), Inorg. Chem.2007, 46, 10221-10228.
5. Wang XT, Wang ZM, Gao S*, “Honeycomb Layer of Cobalt(II) Azide Hydrazine Showing Weak Ferromagnetism”, Inorg. Chem.2007, 46, 10452-10454.
6. Wang ZM*, Zhang B, Zhang YJ, Kurmoo M, Liu T, Gao S*, Kobayashi, H*, “A family of porous magnets, [M₃(HCOO)₆] (M = Mn, Fe, Co and Ni)”, Polyhedron 2007, 26, 2207-2215.
7. Wang ZM*, Zhang YJ, Liu T, Kurmoo M, Gao S*, “[Fe₃(HCOO)₆]: A permanent porous diamond framework displaying H-2/N-2 adsorption, guest inclusion, and guest-dependent magnetism”, Adv. Funct. Mater. 2007, 17, 1523-1536.
8. Xu HB, Wang ZM, Liu T, Gao S*, “Synthesis, structure, and magnetic properties of (A)[Fe^III(oxalate)Cl₂] (A = alkyl ammonium cations) with anionic 1D [Fe^III(oxalate)Cl₂]^- chains”, Inorg. Chem. 2007, 46, 3089-3096.
9. Wang XY, Wang ZM, Gao S*, “A pillared layer MOF with anion-tunable magnetic properties and photochemical [2+2] cycloaddition”, Chem. Commun. 2007, 1127-1129.
10. Zhang W, Zhao F, Liu T, Yuan M, Wang ZM*, Gao S*, “Spin crossover in a series of iron(II) complexes of 2-(2-alkyl-2H-tetrazol-5-yl)-1,10-phenanthroline: Effects of alkyl side chain, solvent, and anion”, Inorg. Chem. 2007, 46, 2541-2555.
11. Zhang B*, Wang ZM*, Kurmoo M, Gao S, Inoue K, Kobayashi H*, “Guest-induced chirality in the ferrimagnetic nanoporous diamond framework Mn₃(HCOO)₆”, Adv. Funct. Mater. 2007, 17, 577-584.
12. Zhu WH, Wang ZM*, Gao S*, “Two 3D porous lanthanide-fumarate-oxalate frameworks exhibiting framework dynamics and luminescent change upon reversible de- and rehydration”, Inorg. Chem. 2007, 46, 1337-1342.
13. Wang ZM*, Zhang B, Inoue K, Fujiwara H, Otsuka T, Kobayashi H*, Kurmoo M, “Occurrence of a rare 4⁹·6⁶ structural topology, chirality, and weak ferromagnetism in the [NH₄][M^II(HCOO)₃] (M = Mn, Co, Ni) frameworks”, Inorg. Chem. 2007, 46, 437-445.

2006

1. Zhang YZ, Wang ZM, Gao S*, “Three-dimensional heterometallic chiral Cr-Mn compound constructed by cyanide and dicyanamide bridges”, Inorg. Chem. 2006, 45, 10404-10406.
2. Liu T, Chen YH, Zhang YJ, Wang ZM*, Gao S*. “NaCl-type frameworks of [M(pyrazine)₂NO₂]ClO₄ (M) Co, Cu), the first examples containing mu 1,3-nitrito bridges showing antiferromagnetism”, Inorg. Chem. 2006, 45, 9148-9150.
3. Wang ZM*, Zhang YJ, Kurmoo M*, Liu T, Vilminot S, Zhao B, Gao S*, “[Zn₃(HCOO)₆]: A porous diamond framework conformable to guest inclusion”, Aust. J. Chem. 2006, 59, 617-628.
4. He Z, Wang ZM*, Gao S, Yan CH*, “Coordination polymers with end-on azido and pyridine carboxylate N-oxide bridges displaying long-range magnetic ordering with low dimensional character”, Inorg. Chem. 2006, 45, 6694-6705.
5. Zhang YZ, Wernsdorfer W, Pan F, Wang ZM, Gao S*, “An azido-bridged disc-like heptanuclear cobalt(II) cluster: towards a single-molecule magnet”, Chem. Commun. 2006, 3302-2006.
6. Zhang YZ, Wang ZM, Gao S*, “Heterometallic Cr-Mn complexes containing cyanide and oxalate bridges’, Inorg. Chem. 2006, 45, 5447-5454.
7. Liu T, Zhang YJ, Wang ZM*, Gao S*, “Two chain compounds of [M(N₃)₂(HCOO)][(CH₃)₂NH₂] (M = Fe and Co) with a mixed azido/formato bridge displaying metamagnetic behavior”, Inorg. Chem. 2006, 45, 2782-2784.
8. Zhu WH, Wang ZM*, Gao S*, “A 3D porous lanthanide-fumarate framework with water hexamer occupied cavities, exhibiting a reversible dehydration and rehydration procedure”, Dalton Trans. 2006, 765-768.
9. Wang XY, Wang L, Wang ZM, Gao S*, “Solvent-tuned azido-bridged Co²⁺ layers: Square, honeycomb, and Kagome”, J. Am. Chem. Soc. 2006, 128, 674-675.
10. Stride JA*, Kurmoo M, Wang ZM, “Investigations of guest-modulated ordering temperatures in open-framework 3D porous magnets”, Phys. B. Conds. Matter 2006, 385, 465-467.
11. Cui HB, Wang ZM, Takahashi K, Okano Y, Kobayashi H*, Kobayashi A, “Ferroelectric porous molecular crystal, [Mn₃(HCOO)₆](C₂H₅OH), exhibiting ferrimagnetic transition”, J. Am. Chem. Soc. 2006, 128, 15074-15075.
12. Huang QC*, Wang ZM, Chu QL, Zhu SZ*, “Crystal structure of a supramolecular complex formed between 1-bromo-2-iodo-tetrafluoroethane and N,N,N ',N '-tetramethyl-ethylenediamine”, J. Incl. Phen. Macrocyc. Chem. 2006, 54 177-180.
13. Zhang B*, Wang ZM, Zhang Y, Takahashi K, Okano Y, Cui HB, Kobayashi H*, Inoue K, Kurmoo M, Pratt FL, Zhu DB*, “Hybrid organic-inorganic conductor with a magnetic chain anion: k-BETS₂[Fe^III(C₂O₄)Cl₂] [BETS = bis(ethylenedithio)tetraselenafulvalene]”, Inorg. Chem. 2006, 45, 3275-3280.

2005

1. Chang F, Wang ZM*, Sun HL, Gao S*, Wen GH, Zhang XX, “{[Cu₂(bpdado)₂(H₂O)₂]·H₂O}_n: A 1D nanotubular coordination polymer with wall made of edge-sharing hexagons, where bpdado=2,2 '-bipyridine-3,3 '-dicarboxylate-1,1 '-dioxide”, Dalton Trans. 2005, 2976-2978, inside front cover
2. He Z, Wang ZM*, Yan CH*, “Ligand-controlled dimensionality: 1D, 2D and 3D Gd(III) coordination polymers based on SO₄^2- and pyridine carboxylate N-oxide ligands”, CrystEngComm. 2005, 7, 143-150.
3. He Z, Gao EQ, Wang ZM*, Yan CH*, Kurmoo M, “Coordination polymers based on inorganic lanthanide(III) sulfate skeletons and an organic isonicotinate N-oxide connector: Segregation into three structural types by the lanthanide contraction effect”, Inorg. Chem. 2005, 44, 862-874.
4. Wang ZM*, Zhang B, Kurmoo M, Green MA, Fujiwara H, Otsuka T, Kobayashi H*, “Synthesis and characterization of a porous magnetic diamond framework, Co₃(HCOO)₆, and its N₂ sorption characteristic”, Inorg. Chem. 2005, 44, 1230-1237.
5. Wang XY, Wang L, Wang ZM, Su G, Gao S*, “Coexistence of spin-canting, metamagnetism, and spin-flop in a (4,4) layered manganese azide polymer”, Chem. Mater. 2005, 17, 6369-6380.
6. Zhang YZ, Wei HY, Pan F, Wang ZM, Chen ZD,* Gao S*, “Two molecular tapes consisting of serial or parallel azido-bridged eight-membered copper rings”, Angew. Chem. Int. Ed. 2005, 44, 5841-5846.
7. Zhang B*, Wang ZM, Fujiwara H, Kobayashi H*, Kurmoo M, Inoue K, Mori T, Gao S, Zhang Y, Zhu DB*, “Tetrathiafulvalene [Fe^III(C₂O₄)Cl₂]: An organic-inorganic hybrid exhibiting canted antiferromagnetism”, Adv. Mater. 2005, 17, 1988-1991.
8. Cui HB, Takahashi K, Kano Y, Kobayashi H*, Wang ZM, Kobayashi A, “Dielectric properties of porous molecular crystals that contain polar molecules”, Angew. Chem. Int. Ed. 2005, 44, 6508-6512.
9. Zhang YZ, Gao S,* Wang ZM, Su G, Sun HL, Pan F, “Rational synthesis and magnetic properties of a family of low-dimensional heterometallic Cr-Mn complexes based on the versatile building block [Cr(2,2 '-bipyridine)(CN)₄]^-”, Inorg. Chem. 2005, 44, 4534-4545.
10. Sun HL, Wang ZM, Gao S*, “Synthesis, crystal structures, and magnetism of cobalt coordination polymers based on dicyanamide and pyrazine-dioxide derivatives”, Inorg. Chem. 2005, 44, 2169-2176.
11. Wang XY, Wei HY, Wang ZM, Chen ZD*, Gao S*, “Formate - The analogue of azide: Structural and magnetic properties of M(HCOO)₂(4,4 '-bpy)·nH₂O (M=Mn, Co, Ni; n=0, 5)”, Inorg. Chem. 2005, 44, 572-583.

Before 2005 (selected)

1. Wang ZM*, Zhang B, Otsuka T, Inoue K, Kobayashi H*, Kurmoo M, “Anionic NaCl-type frameworks of [Mn^II(HCOO)₃^-], templated by alkylammonium, exhibit weak ferromagnetism”, Dalton Trans. 2004, 2209-2216.
2. Wang ZM*, Zhang B, Fujiwara H, Kobayashi H*, Kurmoo M, “Mn₃(HCOO)₆: a 3D porous magnet of diamond framework with nodes of Mn-centered MnMn4 tetrahedron and guest-modulated ordering temperature”, Chem. Commun. 2004, 416-417.
3. He Z, He C, Wang ZM*, Gao EQ, Liu Y, Yan CH*, “Self-assembly of molecular squares based on easy-to-prepare multidentate Schiff base ligands”, Dalton Trans. 2004, 502-504.
4. He Z, He C, Gao EQ, Wang ZM*, Yang XF, Liao CS, Yan CH*, “Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block”, Inorg. Chem. 2003, 42, 2206-2208.
5. Wang ZM, Sun BW, Luo J, Gao S, Liao CS, Yan CH*, Li Y, “Bimetallic sandwiches assembled with chelated Cu/Zn cations and manganese dicyanamide polymeric ladders”, Polyhedron, 2003, 22, 433-439.
6. Xu G, Wang ZM*, He Z, Lu Z, Liao CS, Yan CH*, “Synthesis and structural characterization of nonanuclear lanthanide complexes”, Inorg. Chem. 2002, 41, 6802-6807.
7. Cheng YJ, Wang ZM*, Liao CS, Yan CH*, “Novel sheet-like supramolecular architectures constructed from infinite hydrogen-bonded, protonated adenine water halide and polyiodide ribbons”, New J. Chem. 2002, 26, 1360-1364.
8. Wang ZM, Sun BW, Luo J, Gao S, Liao CS, Yan CH*, Li Y, “Bimetallic sheet and 3D threefold interpenetrating diamond-like network constructed by chelate Cu cations and Mn dicyanamide polymeric chains. Synthesis, crystal structure, and magnetism of [CuL₂][Mn(dca)₄] (L = ethylenediamine or 1,3-diaminopropane; dca = dicyanamide N(CN)₂^-)”, Inorg. Chim. Acta 2002, 332, 127-134.
9. Wang ZM, Cheng YJ, Liao CS, Yan CH*, “The first supramolecular architectures assembled by infinite hydrogen-bonded, protonated nucleobase-water ribbons and unusual polyiodide frameworks”, CrystEngComm. 2001, art no. 50.